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Associated with the uptake of energy of quantized absorption is some deactivation mechanism whereby the atom or molecule returns to its original state. Associated with the loss of energy by emission of a quantum of energy or photon is some prior excitation mechanism. Both of these associated mechanisms are represented by the dotted lines in Figure 1.3.

P(X(0) > u) + P(Uu 1, X (0) u) P(E) P(M > u)

1.25 2 X 1=14.280; S1 =0.0280;

X(t) = x, Xj (t) = 0 pX(t),Xj (t) (x, 0) j (dt). It is clear that for every real x, |p E (x) pM (x)| p(x) pM (x),

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Schiff-base bridges, 45 46 Schiff-base ligands, tetradentate condensation with premade ligands, 47 49 metal derivative electrochemical polymerizations, 64 65 synthesis during condensation, 51 52 exercise, 92 Schiff-base metal polymers conductivity cerium(IV), 215 216 doped, 215 216 zirconium, 215 216 copper(II) Langmuir-Blodgett lms, 226 syntheses, 47 49, 51 52, 64 65 SEC, see Gel permeation chromatography Semiconductors band gap variation, 213 214 conductivity, 213 214 doping, 214 Semimetal conductivity, 213 214 Sesquisiloxane step polymerization, 55 56 Shear, shear modulus, shear stress, shear strain, 168 170 Shear rate, 170 Shish kebob phthalocyanine polymers, 13 14 conductivities, 214 215 solubilizing, 41 42 step condensation synthesis, 54 Silanes, see Polysilanes Silica aerogels for oxygen sensing, 226 Silicates single-chain structure, 5 Silicon-29 NMR peak shifts, 134 Silicon coupling agents, 186 188 Silicones, see Polysiloxanes Silicon luminescent polymer, 221 222 Silicon nitride from silicon tetraamide, 83 Silicon phthalocyanine polymers, 42 Siloxane bridges, 31 Siloxane-carborane elastomers, 186 Dexsil, 53 synthesis, 53 Siloxanes, see also Polysiloxanes structure, 26 Silphenylene-siloxane polymers, 54 55 Silver coordination polymer structure, 6, 84 85 Silver alkyls as radical initiators, 60 61 Silver wool as ring opening catalyst, 77 78

generated are called unsupervised methods, whereas methods that make use of the response variable to guide group generation are called supervised methods For example, a data set of cars could be grouped using an unsupervised method The groups generated would be based on general classes of cars Alternatively, we could group the cars using car fuel ef ciency to direct the grouping This would generate groups directed towards nding hidden relationships between groups of cars and car fuel ef ciency Now, if we were to repeat the exercise using a different goal, for example, car acceleration, the data would be grouped differently In this situation the groups are directed towards nding hidden relationships associated with car acceleration Type of variables: Certain grouping methods will only accept categorical data, whereas others only accept continuous data Other techniques handle all types of data.

6.3.1.6 802.1X Authentication The IEEE developed a standard for local and metropolitan area networks, specifically covering port-based network access control [11]. Many network environments have a number of physical ports that are exposed to unauthorized access. These physical ports are available for access and require logical controls to avoid security incidents. This situation is applicable to the IPTV environment, specifically for set top boxes and their connections to the DSLAM ports (via the residential gateway). The purpose of the standard is to allow very restricted communication between a newly connected host and a validating host until the identity has been verified and access is granted. Connected devices are known as supplicants, intermediaries are known as authenticators (in this case the DSLAM) and there is an authentication server who would make the final decision (in this case the RADIUS server using EAP). The supplicant starts an 802.1X request using EAPoL. This is received by the authenticator and forwarded to the authentication server using EAP/RADIUS as part of the negotiation. Once the authentication server has verified and authorized the supplicant, then the port configuration

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